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The difference between silicone resin and silicone and the use of silicone resin

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Although silicone resin and silicone are similar in name, they are actually two different materials with different chemical structures and characteristics.
I. Differences between silicone resin and silicone
  1. Different chemical structures:
    • Silicone: Silicone, or silicone compound, refers to a compound containing Si-C bonds and at least one organic group directly connected to a silicon atom. Compounds that connect organic groups to silicon atoms through elements such as oxygen, sulfur, and nitrogen are also often regarded as silicone compounds. Polysiloxane is the most common type, with a siloxane bond (-Si-O-Si-) as the backbone, accounting for more than 90% of silicone compounds. It has the following characteristics:
      • Sufficient methyl groups on the Si atom shield the high-energy polysiloxane main chain.
      • The C-H bond is non-polar, making the intermolecular interaction very weak.
      • The Si-O bond is long, and the Si-O-Si bond angle is large.
      • The Si-O bond is a covalent bond with 50% ionic bond characteristics (covalent bonds are directional, while ionic bonds are non-directional).
    • Silicone resin: It is a highly cross-linked network structure of polyorganosiloxane and often contains hydroxyl groups. Its structure contains not only organic groups but also the characteristics of inorganic materials.
  2. Different preparation methods:
    • Silicone: Silicone compounds can be synthesized by various methods, such as connecting through oxygen, sulfur, nitrogen and other elements to organic groups.
    • Silicone resin: Its preparation usually involves using a mixture of methyltrichlorosilane, dimethyldichlorosilane, etc., hydrolyzing in an organic solvent, and then forming a highly cross-linked three-dimensional network structure through a polycondensation reaction.
  3. Different performance characteristics:
    • Silicone: Due to its unique structure (such as methyl groups on the Si atom shielding the main chain, non-polar C-H bonds, etc.), silicone materials have good heat resistance, electrical properties, water resistance, weather resistance, and certain mechanical strength.
    • Silicone resin: It has low mechanical strength, poor solvent resistance, and poor adhesion to substrates such as metals and plastics. In addition, the compatibility of silicone resin is limited and needs to be modified to be compatible with other organic resins.

II. Uses of silicone resin
Silicone resin is mainly used in the preparation of silicone insulating varnishes, silicone coatings, silicone adhesives, and silicone plastics. High-grade architectural exterior wall coatings and other high-performance coatings are the main markets for silicone resins. The main varieties are modified polyester and modified acrylic resins. In addition, the consumption of silicone resins in the electronics/electrical industry is growing relatively fast and will also be an important driving force for the global development of silicone resins in the future. It has a very wide range of applications.
  1. Electrical insulating varnish: Used for coil impregnating varnish, glass cloth impregnating varnish, mica bonding insulating varnish, and silicone varnish for electronic and electrical protection of electrical machinery and appliances to improve the insulating performance of equipment.
  2. Coating: Due to its heat resistance, cold resistance, weather resistance, and water repellency, silicone resin is used to make colorless, transparent coatings with good adhesion and wear resistance, such as anti-sticking release coatings and moisture-proof and water-repellent coatings.
  3. Adhesive: Divided into silicone type and silicone resin type, used for various adhesion needs, such as pure silicone resin type and modified resin type, suitable for different substrates.
  4. Plastic: Used to manufacture silicone plastics with heat resistance, insulation, flame retardancy, and arc resistance, such as packaging plastics and foam plastics for semiconductor component housings.
  5. Micropowder and ladder polymer: Silicone resin micropowder has low relative density, heat resistance, weather resistance, lubricity, and water repellency, and is suitable for specific industrial applications.
  6. High-temperature resistant structural adhesive: By copolymerizing and modifying with organic resins such as polyester, epoxy, or phenolic resin, it provides high-temperature resistance and excellent mechanical properties.
  7. Electronics industry: Methyl MQ silicone resin is widely used in the electronics industry, such as in integrated circuit packaging and fixing glue for electronic components, providing electrical insulation and high-temperature resistance.
  8. Chemical industry: As an additive for coatings and adhesives to improve coating performance; as a basic component in optical materials for optical impregnation, optical fiber coating, and optical coating.
  9. Construction industry: Silicone resin is used as a building sealant to improve the sealing and durability of buildings. It can also be used as a film-forming agent for coatings to enhance the corrosion resistance and weather resistance of the coating.
  10. Others: Silicone resin can also be used as a defoaming agent, especially in the food fermentation industry, such as in the production processes of monosodium glutamate, brewing, and soy sauce.

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